A novel approach to phosphonic acids from hypophosphorous acid

被引：49
作者：
Bravo-Altamirano, Karla [1 ]
Montchamp, Jean-Luc [1 ]
机构：
[1] Texas Christian Univ, Dept Chem, Ft Worth, TX 76129 USA
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 33期
关键词：
phosphonic acid; H-phosphinic acid; hypophosphorous acid;
D O I：
10.1016/j.tetlet.2007.06.090
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel access to phosphonic acids via Pd-catalyzed tandem carbon-phosphorus bond formation-oxidation processes was developed. The procedures involve atom-economical and environmentally friendly functionalization reactions of hypophosphorous acid (H3PO2) and H-phosphinic acids [RP(O)(OH)(H)]. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5755 / 5759
页数：5
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