Excess molar volumes and excess Gibbs energies in N-methylformamide+water, or +methanol, or +ethanol at the temperature 303.15K

被引:26
作者
Zielkiewicz, J [1 ]
机构
[1] Gdansk Tech Univ, Dept Chem, PL-80952 Gdansk, Poland
关键词
D O I
10.1021/je980001v
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess volumes V-E measured in a dilution dilatometer and total vapor pressures at the temperature 303.15 K are reported for (N-methylformamide + water), (N-methylformamide + methanol), and (N-methylformamide + ethanol) over the entire composition range. The total vapor pressure measurements were made by a modified static method. The excess molar volumes are negative for all, the mixtures over the entire composition range; the vapor pressure measurements show only small negative deviations from ideality for these systems.
引用
收藏
页码:650 / 652
页数:3
相关论文
共 9 条
[1]   THERMODYNAMICS OF AQUEOUS MIXTURES OF NON-ELECTROLYTES .1. EXCESS VOLUMES OF WATER-N-ALCOHOL MIXTURES AT SEVERAL TEMPERATURES [J].
BENSON, GC ;
KIYOHARA, O .
JOURNAL OF SOLUTION CHEMISTRY, 1980, 9 (10) :791-804
[2]  
Boublik T., 1984, PHYS SCI DATA, V17
[3]   IMPROVED DILUTION DILATOMETER FOR MEASUREMENTS OF EXCESS VOLUMES [J].
KUMARAN, MK ;
MCGLASHAN, ML .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1977, 9 (03) :259-267
[4]   EXCESS MOLAR VOLUMES AND APPARENT MOLAR VOLUMES OF SOME AMIDE PLUS WATER-SYSTEMS AT 303.15 AND 308.15 K [J].
PAL, A ;
SINGH, YP .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (04) :818-822
[5]  
STEPHENSON RM, 1987, HDB THERMODYNAMICS
[6]   EXCESS VOLUMES OF (N,N-DIMETHYLFORMAMIDE PLUS ETHANOL PLUS WATER) AT THE TEMPERATURE 313.15-K [J].
ZIELKIEWICZ, J .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1994, 26 (12) :1317-1322
[7]   EXCESS VOLUMES IN (N-METHYLFORMAMIDE PLUS METHANOL PLUS WATER) AT THE TEMPERATURE 313.15 K [J].
ZIELKIEWICZ, J .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1995, 27 (11) :1275-1279
[8]   (Vapour plus liquid) equilibria in (N-methylformamide plus ethanol plus water) at the temperature 313.15 K [J].
Zielkiewicz, J .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1997, 29 (02) :229-237
[9]  
ZIELKIEWICZ J, 1990, FLUID PHASE EQUILIBR, V58, P191