A tristable [2]rotaxane that is doubly gated by foldamer and azobenzene kinetic barriers

被引:18
作者
Wang, Wei-Kun [1 ]
Xu, Zi-Yue [1 ]
Zhang, Yun-Chang [1 ]
Wang, Hui [1 ]
Zhang, Dan-Wei [1 ]
Liu, Yi [2 ]
Li, Zhan-Ting [1 ]
机构
[1] Fudan Univ, Dept Chem, Collaborat Innovat Ctr Chem Energy Mat iChEM, 220 Handan Rd, Shanghai 200433, Peoples R China
[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, One Cyclotron Rd,MS 67R6110, Berkeley, CA 94720 USA
基金
美国国家科学基金会;
关键词
MOLECULAR MOTORS; AROMATIC AMIDE; DIMERIZATION; ARCHITECTURES; MACHINES; MUSCLES; SWITCH;
D O I
10.1039/c6cc02110g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A hydrogen bonded foldamer unit and an azobenzene unit have been incorporated into the linear component of a tristable [2]rotaxane to give rise to a doubly gated switching system tuned by the folding-defolding of the foldamer unit and the photo-initiated trans-cis isomerization of the azobenzene unit.
引用
收藏
页码:7490 / 7493
页数:4
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