Chemical reactivity of [Os3W(mu-H)(CO)(14)](-) anion; Synthesis and X-ray crystal structure of [Os3W(mu-H)(CO)(12){mu(3)-eta(3)-C(H)C(Ph)C(OH)}]

被引：0

作者：

Hui, JWS ^{[1
]}

Wong, WT ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

POLYHEDRON | 1996年 / 15卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of [Os3W(mu-H)(mu-CO)(CO)(13)](-) anion with phenylacetylene in CHCl3 gave [Os3W(mu-H)(CO)(12){mu(3)-eta(3)-C(H)C(Ph)C(OH)}] in moderate yield. The compound has been fully characterized by both spectroscopic and crystallographic methods. Coupling of a phenylacetylene and a carbonyl ligand to form a cluster bound {mu(3)-eta(3)-C(H)C(Ph)C(OH)} moiety is observed.

引用

页码：541 / 543

页数：3

共 50 条

[41] DECACARBONYLDI-MU-HYDRIDOTRIOSMIUM - OS3(MU-H)2(CO)10
KAESZ, HD
INORGANIC SYNTHESES, 1990, 28 : 238 - 240
[42] KINETICS AND MECHANISM OF REDUCTIVE ELIMINATION OF HYDROCARBONS FROM (MU-H)3RU3(MU-3CPH)(CO)9, (MU-H)3RUE(MU-3CET)(CO)9, (MU-H)3RUE(MU-3-CCL)(CO)9, (MU-H)3RU3(MU-3CCO2ME)(CO)9, (MU-H)3RU3(MU-3-CSET)(CO)9, (MU-H)3RU3(MU-3CCHPHCH2PH)(CO)9
DUGGAN, TP
GOLDEN, MJ
KEISTER, JB
ORGANOMETALLICS, 1990, 9 (05) : 1656 - 1665
[43] Reduction of the unique carbonyl in (mu-H)(2)Os-3(CO)(9)(mu(3)-CCO) by BH3 center dot THF. Molecular structure of (mu-H)(3)Os-3(CO)(9)(mu(3)-CCH3)
Bauer, JAK
Chung, JH
Boyd, EP
Liu, JP
Strickland, DS
Kneuper, HJ
Shapley, JR
Shore, SG
INORGANIC CHEMISTRY, 1996, 35 (05) : 1405 - &
[44] The crystal, molecular and electronic structure of [Os-3(mu-H)(CO)(10)(mu-PPh2)]
Johnson, BFG
Lewis, J
Nordlander, E
Raithby, PR
Housecroft, CE
INORGANICA CHIMICA ACTA, 1997, 259 (1-2) : 345 - 350
[45] SURFACE ORGANOMETALLIC CHEMISTRY - HYDROGENATION OF ETHYLENE WITH OS3(CO)10(MU-H)(MU-OSI[-) AND OS3(CO)10(MU-H)(MU-OPH) - EVIDENCE FOR CLUSTER CATALYSIS
CHOPLIN, A
BESSON, B
DORNELAS, L
SANCHEZDELGADO, R
BASSET, JM
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (09) : 2783 - 2787
[46] REACTION OF SULFUR-DIOXIDE WITH THE UNSATURATED TRIOSMIUM PLATINUM CLUSTERS OS3PT(MU-H)2(CO)10(PC-C6H11,C6H5)3 - X-RAY CRYSTAL-STRUCTURE OF OS3PT(MU-H)2(MU-SO2)(CO)10(PCY3)
EWING, P
FARRUGIA, LJ
ORGANOMETALLICS, 1989, 8 (07) : 1665 - 1673
[47] DERIVATIVES OF THE TYPE OS4(MU-H)(CO)14(ER3) (E = SI, GE, SN, R = ME, PH) - STRUCTURE OF OS4(MU-H)(CO)14(SNME3)
LU, CY
EINSTEIN, FWB
JOHNSTON, VJ
POMEROY, RK
INORGANIC CHEMISTRY, 1989, 28 (23) : 4212 - 4216
[48] REACTION OF PENTAFLUORONITROSOBENZENE WITH [OS3H(MU-H)(CO)10(MPH3)] (M=P, AS, SB) - SYNTHESIS AND X-RAY STRUCTURE OF [OS3(MU-H)(CO)10(PPH3)(ONC6F4O)]
ANG, HG
KWIK, WL
ONG, KK
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 474 (1-2) : 149 - 152
[49] STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES .16. CRYSTAL-STRUCTURE OF (MU-H)(MU-OME)OS3(CO)10 AND A COMPARISON OF THE HINGED OS(MU-H)2OS, OS(MU-H)(MU-OME)OS, AND OS(MU-OME)2OS BRIDGES IN TRINUCLEAR (MU-H)N(MU-OME)2-NOS3(CO)10(N=0-2) COMPLEXES
CHURCHILL, MR
WASSERMAN, HJ
INORGANIC CHEMISTRY, 1980, 19 (08) : 2391 - 2395
[50] GROUP-IV DERIVATIVES OF OS3(MU-H)2(CO)10 - STRUCTURES OF HOS3(MU-H)2(CO)10(SIHPH2) AND OS3(MU-H)2(CO)10(SNME3)2
EINSTEIN, FWB
POMEROY, RK
WILLIS, AC
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (03) : 257 - 268

← 1 2 3 4 5 →