Chemical reactivity of [Os3W(mu-H)(CO)(14)](-) anion; Synthesis and X-ray crystal structure of [Os3W(mu-H)(CO)(12){mu(3)-eta(3)-C(H)C(Ph)C(OH)}]

被引：0

作者：

Hui, JWS ^{[1
]}

Wong, WT ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

POLYHEDRON | 1996年 / 15卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of [Os3W(mu-H)(mu-CO)(CO)(13)](-) anion with phenylacetylene in CHCl3 gave [Os3W(mu-H)(CO)(12){mu(3)-eta(3)-C(H)C(Ph)C(OH)}] in moderate yield. The compound has been fully characterized by both spectroscopic and crystallographic methods. Coupling of a phenylacetylene and a carbonyl ligand to form a cluster bound {mu(3)-eta(3)-C(H)C(Ph)C(OH)} moiety is observed.

引用

页码：541 / 543

页数：3

共 50 条

[1] Chemical reactivity of [Os3W(ae-H)(CO)14] anion: synthesis and X-ray crystal structure of [Os3W(ae-H)(CO)12{ae3-eta3-C(H )C(Ph)C(OH)$ RTBC@]
Polyhedron, 3 (541):
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