Synthesis, structure, and application of [PhNMe2H][B{C6F4C(C6F5)2F}4]

被引：20

作者：

Rodriguez, G ^{[1
]}

Brant, P ^{[1
]}

机构：

[1] ExxonMobil, Baytown Polymers Ctr, Baytown, TX 77521 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 11期

关键词：

D O I：

10.1021/om001080i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new perfluorinated tetraaryl borate [B{C6F4C(C6F5)(2)F}(4)](-) (3) has been prepared and characterized. The X-ray structural analysis of [C6H5N(H)-(CH3)(2)][3] confirms the tetrahedral geometry about the boron. The performance of 3 as a weakly coordinating anion in ethylene polymerization was evaluated and compared with that of B(C6F5)(4)(-) and B(3,5-(CF3)(2)C6H3)(4)(-). The stability of 3 throughout polymerization was evaluated by analyzing anion residues in a polymer sample using mass spectroscopy.

引用

页码：2417 / 2420

页数：4

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