Development of surface properties of ultra-high-molecular-weight polyethylene film using side-chain crystalline block copolymers

被引：4
作者：
Hirai, Sho [1 ]
Ishimoto, Shoichi [2 ]
Phanthong, Patchiya [1 ]
Yao, Shigeru [1 ,2 ]
机构：
[1] Fukuoka Univ, Res Inst Creat Funct & Struct Mat, Jonan Ku, 8-19-1 Nanakuma, Fukuoka 8140180, Japan
[2] Fukuoka Univ, Grad Sch Chem Engn, Jonan Ku, 8-19-1 Nanakuma, Fukuoka 8140180, Japan
来源：
JOURNAL OF POLYMER ENGINEERING | 2020年 / 40卷 / 03期
基金：
日本学术振兴会;
关键词：
adhesion; hydrophilicity; side-chain crystalline block copolymer; surface modification; ultra-high-molecular-weight polyethylene (UHMWPE); ANTIOXIDANT PROPERTIES; MECHANICAL-PROPERTIES; COMPOSITES; POLYMER; IMPROVEMENT;
D O I：
10.1515/polyeng-2019-0311
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Ultra-high-molecular-weight polyethylene (UHMWPE) has been widely used in industry; however, the applications for UHMWPE are limited because of low hydrophilic and adhesive properties. Herein, we developed the surface properties of UHMWPE by using side-chain crystalline block copolymers (SCCBCs), which consist of a side-chain crystalline unit and a functional unit. This process only required immersing the UHMWPE film in the diluted SCCBC solution, which enabled the UHMWPE surface to be coated homogeneously. The results of the contact angle and tensile shear test showed that the surface of UHMWPE modified with SCCBC was improved in hydrophilicity and adhesive properties. In addition, high adhesion strength was measured on UHMWPE surfaces dipped in a SCCBC solution at high temperature with the UHMWPE film becoming elongated at all parts other than the adhesion contact area.
引用
收藏
页码：231 / 236
页数：6
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