Ultrasound-assisted synthesis of a benzimidazole-containing Zn(II) coordination polymer as highly effective Lewis acid catalyst for cycloaddition of epoxides with CO2

被引：5
|
作者：
Liu, Ce [1 ,2 ]
Xing, Zhiqiang [1 ]
Liu, Lin [1 ]
Han, Zheng-Bo [1 ]
机构：
[1] Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
[2] North China Univ Sci & Technol, Coll Chem Engn, Tangshan 063210, Hebei, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2020年 / 113卷
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Catalyst; Carbon dioxide cycloaddition; Ultrasonic synthesis; Zinc(II); METAL-ORGANIC FRAMEWORK; FIXATION; SITES;
D O I：
10.1016/j.inoche.2020.107812
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A micron sized Zn (II) coordination polymer (CP), namely {[Zn(L)(5-mip)]center dot EtOH)(1) (L = 1,3-bis(benzimidazol-1-yl)-2-propanol and 5-H(2)mip = 5-methyisophthalic acid), was synthesized by ultrasonic irradiation at room temperature. The effects of ultrasonic power and time on the morphology and size of 1 were investigated in detail. Interestingly, micron sized 1 with considerable stability is can be used as an excellent and reused heterogeneous catalyst for carbon dioxide cycloaddition to epoxides under mild conditions.
引用
收藏
页数：4
相关论文
共 26 条
  • [11] A Pyridinium-Pyridinium Zinc(II) Porphyrin Ion Porous Organic Polymer as Efficient Heterogeneous Catalyst for Cycloaddition of Epoxides with CO2
    Ma, Linjing
    Su, Zhenping
    Wang, Ning
    Li, Jun
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 26 (14)
  • [12] Cd(<sc>ii</sc>) and Zn(<sc>ii</sc>) coordination polymer-assisted CO2/cyclohexene oxide copolymerization with a double metal cyanide catalyst
    Huang, Zi-Qing
    Chen, Jia-Qi
    Zhang, Xiao-Yu
    Yuan, Cheng-Kai
    Wang, Peng
    Zhao, Yue
    Zhao, Bao-Cheng
    Qi, Wei-Xin
    Sun, Wei-Yin
    CRYSTENGCOMM, 2024, 26 (12) : 1701 - 1709
  • [13] The ultrasound-assisted synthesis of effective monodisperse nickel nanoparticles: magnetic characterization and its catalytic activity in CO2 methanation
    Vargas, E.
    Romero-Saez, M.
    Denardin, J. C.
    Gracia, F.
    NEW JOURNAL OF CHEMISTRY, 2016, 40 (09) : 7307 - 7310
  • [14] A highly ordered mesoporous polymer supported imidazolium-based ionic liquid: an efficient catalyst for cycloaddition of CO2 with epoxides to produce cyclic carbonates
    Zhang, Wei
    Wang, Qixiang
    Wu, Haihong
    Wu, Peng
    He, Mingyuan
    GREEN CHEMISTRY, 2014, 16 (11) : 4767 - 4774
  • [15] A porous Zn(II)-coordination polymer based on a tetracarboxylic acid exhibiting selective CO2 adsorption and iodine uptake
    Arici, Mursel
    Arici, Tugba Alp
    Demiral, Hakan
    Tas, Murat
    Yesilel, Okan Zafer
    DALTON TRANSACTIONS, 2020, 49 (31) : 10824 - 10831
  • [16] Rapid sonochemical synthesis of highly active and stable 2-D inorganic-organic hybrid catalyst for solvent-free CO2 cycloaddition with epoxides
    Beniwal, Naveen
    Sangeeta
    Singh, Lovjeet
    Rekha, Pawan
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1320
  • [17] Unveiling dual catalysis enhancement of a pyridinium-containing Zn(ii) coordination polymer in aerobic photooxidation of organic substrates and selective photoreduction of CO2
    Fang, Youting
    Chao, Duobin
    JOURNAL OF MATERIALS CHEMISTRY A, 2023, 11 (39) : 21373 - 21382
  • [18] Thermally activated bipyridyl-based Mn-MOFs with Lewis acid-base bifunctional sites for highly efficient catalytic cycloaddition of CO2 with epoxides and Knoevenagel condensation reactions
    Xu, Zhen
    Zhao, Ya-Yu
    Chen, Le
    Zhu, Cai-Yong
    Li, Peng
    Gao, Wei
    Li, Ji-Yang
    Zhang, Xiu-Mei
    DALTON TRANSACTIONS, 2023, 52 (12) : 3671 - 3681
  • [19] Thermally activated construction of open metal sites on a Zn-organic framework: An effective strategy to enhance Lewis acid properties and catalytic performance for CO2 cycloaddition reactions
    Zhang, Jie
    Zou, Moliang
    Li, Qing
    Dai, Weili
    Wang, Dan
    Zhang, Shuqu
    Li, Bing
    Yang, Lixia
    Luo, Shenglian
    Luo, Xubiao
    APPLIED SURFACE SCIENCE, 2022, 572
  • [20] Dual hydrogen-bond donor group-containing Zn-MOF for the highly effective coupling of CO2 and epoxides under mild and solvent-free conditions
    Gao, Ziyu
    Zhang, Xiao
    Xu, Ping
    Sun, Jianmin
    INORGANIC CHEMISTRY FRONTIERS, 2020, 7 (10) : 1995 - 2005
123