Constructing graphene nanosheet-supported FeOOH nanodots for hydrogen storage of MgH2

Novel graphene-supported FeOOH nanodots (FeOOH NDs@G) were successfully prepared by a facile hydrothermal method and doped into MgH2 through mechanical ball-milling. MgH2 with 10wt% FeOOH NDs@G began to release hydrogen at 229.8 degrees C, which is 106.8 degrees C lower than that of pure MgH2. The MgH2-10wt% FeOOH NDs@G composite could reversibly absorb 6.0wt% hydrogen at 200 degrees C under a 3.2 MPa hydrogen pressure within 60 min. With the addition of FeOOH NDs@G, the dehydrogenation and hydrogenation activation energy of MgH2 was decreased to 125.03 and 58.20 kJ center dot mol(-1) (156.05 and 82.80 kJ center dot mol(-1) for pure MgH2), respectively. Furthermore, the hydrogen capacity of the FeOOH NDs@G composite retained 98.5% of the initial capacity after 20 cycles, showing good cyclic stability. The catalytic action of FeOOH NDs@G towards MgH2 could be attributed to the synergistic effect between graphene nanosheets and in-situ formed Fe, which prevented the aggregation of Mg/MgH2 particles and accelerated the hydrogen diffusion during cycling, thus enabling the MgH2-10wt% FeOOH NDs@G composite to exhibit excellent hydrogen storage performance.