In-line, roll-to-roll morphology analysis of organic solar cell active layers

被引：54

作者：

Rossander, Lea Hildebrandt ^{[1
]}

Dam, Henrik Friis ^{[1
]}

Carle, Jon Eggert ^{[1
]}

Helgesen, Martin ^{[1
]}

Rajkovic, Ivan ^{[2
]}

Corazza, Michael ^{[1
]}

Krebs, Frederik Christian ^{[1
]}

Andreasen, Jens Wenzel ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Energy Convers & Storage, DK-4000 Roskilde, Denmark

[2] Stanford Synchrotron Radiat Lightsource, Menlo Pk, CA 94025 USA

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2017年 / 10卷 / 11期

基金：

欧洲研究理事会;

关键词：

POLYMER; POLY(3-HEXYLTHIOPHENE); CRYSTALLINE; ELECTRONICS; FABRICATION;

D O I：

10.1039/c7ee01900a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present the first comparative in situ small and wide angle X-ray scattering study of two polymers that are relevant for organic photovoltaics, during coating on a flexible substrate. From the obtained measurements we identified several differences between the drying of the two polymers. The polymer optimized for roll-to-roll coating attained its final morphological packing nearly instantly after deposition, and had the shortest drying profile. We therefore conclude that fast-drying polymers which are influenced less by drying temperature or substrate inhomogeneities are better suited for roll-to-roll coating, and that fundamentally, the kinetics of drying dominate the process in the case of roll-to-roll slot-die coating.

引用

页码：2411 / 2419

页数：9

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