Production of biobased HMF derivatives by reductive amination

被引：73

作者：

Cukalovic, Ana ^{[1
]}

Stevens, Christian V. ^{[1
]}

机构：

[1] Fac Biosci Engn, SynBioC Res Grp, Dept Organ Chem, B-9000 Ghent, Belgium

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 07期

关键词：

ION-EXCHANGE-RESIN; D-FRUCTOSE; DEHYDRATION; CONVERSION; SOLVENT; GLUCOSE; LIQUIDS; BIOMASS; IMINES; WATER;

D O I：

10.1039/c002340j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5-(Hydroxymethyl) furfural (HMF) has recently attracted a significant amount of revived attention as a renewable building block for conversion to a wide range of useful derivatives. A simple procedure for the conversion of HMF to (5-alkyl- and 5-arylaminomethyl-furan-2-yl)methanol has now been developed. Reactions were conducted without the use of a catalyst and under very mild conditions. As a proof of concept, a small library of derivatives was produced from HMF and several aliphatic and aromatic amines in high yields and requiring only minimal purification. This route presents a novel way for the production of furan-based renewable building blocks.

引用

页码：1201 / 1206

页数：6

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