Design and testing of a microchannel reactor for the PROX reaction

被引：35
作者：
Cruz, S. [1 ]
Sanz, O. [1 ]
Poyato, R. [1 ]
Laguna, O. H. [1 ]
Echave, F. J. [2 ]
Almeida, L. C. [2 ]
Centeno, M. A. [1 ]
Arzamendi, G. [3 ]
Gandia, L. M. [3 ]
Souza-Aguiar, E. F. [4 ]
Montes, M. [2 ]
Odriozola, J. A. [1 ]
机构：
[1] Univ Seville, CSIC, Inst Mat Sci Seville, Seville 41092, Spain
[2] Univ Basque Country, Dept Appl Chem, San Sebastian 20018, Spain
[3] Univ Publ Navarra, E-31006 Pamplona, Spain
[4] Petrobras SA, Rio De Janeiro, Brazil
来源：
CHEMICAL ENGINEERING JOURNAL | 2011年 / 167卷 / 2-3期
关键词：
Microchannel reactor; CO-PROX; CuOx-CeO2; Transient liquid phase bonding; Al-alloyed ferritic stainless steel; PREFERENTIAL CO OXIDATION; CARBON-MONOXIDE; SELECTIVE OXIDATION; CUO-CEO2; CATALYSTS; COMPOSITE CATALYSTS; MICRO-REACTOR; OXIDE; CERIA; COPPER; MICROREACTOR;
D O I：
10.1016/j.cej.2010.08.088
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The different steps for manufacturing a microchannel reactor for the PROX reaction are discussed. Transient Liquid Phase bonding (TLP) using a Ni-B-Si amorphous melt spun is used for joining micromilled Al-alloyed ferritic stainless steel plates followed by recrystallization at 1200 degrees C for 5 h. A CuOx-CeO2 catalyst synthesized by the coprecipitation method was washcoated on the microchannel block resulting in a homogenous 20-30 mu m thick layer. The catalytic activity for CO-PROX reaction is similar in both the powder catalyst and the microchannel coated reactor but the selectivity is higher in the microchannel reactor. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：634 / 642
页数：9
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