Applications of Lawesson's reagent in organic and organometallic syntheses

被引:275
作者
Jesberger, M [1 ]
Davis, TP [1 ]
Barner, L [1 ]
机构
[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia
来源
SYNTHESIS-STUTTGART | 2003年 / 13期
关键词
Lawesson's reagent; thionation; organothiophosphorus reagent; heterocycles; sulfur-compounds; organometallic compounds;
D O I
10.1055/s-2003-41447
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review, including 245 references, describes the application of Lawesson's reagent [2,4-bis(p-methoxyphenyl)-1,3-dithiaphosphetane-2,4-disulfide] LR in organic and organometallic syntheses. Thionations of carbonyl-containing compounds as well as unexpected reactions are shown for different applications (e.g. cyclizations, rerrangements, syntheses of heterocyclic compounds etc.). Syntheses of novel organometallic compounds by LR are also discussed.
引用
收藏
页码:1929 / 1958
页数:30
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