Applications of Lawesson's reagent in organic and organometallic syntheses

被引：278

作者：

Jesberger, M ^{[1
]}

Davis, TP ^{[1
]}

Barner, L ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

来源：

SYNTHESIS-STUTTGART | 2003年 / 13期

关键词：

Lawesson's reagent; thionation; organothiophosphorus reagent; heterocycles; sulfur-compounds; organometallic compounds;

D O I：

10.1055/s-2003-41447

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review, including 245 references, describes the application of Lawesson's reagent [2,4-bis(p-methoxyphenyl)-1,3-dithiaphosphetane-2,4-disulfide] LR in organic and organometallic syntheses. Thionations of carbonyl-containing compounds as well as unexpected reactions are shown for different applications (e.g. cyclizations, rerrangements, syntheses of heterocyclic compounds etc.). Syntheses of novel organometallic compounds by LR are also discussed.

引用

页码：1929 / 1958

页数：30

共 250 条

[1] ALPHA-METHYLENE BETA-S-THIOLACTONES - SYNTHESIS OF A NEW HETEROCYCLE BY SULFURIZATION OF AN ALPHA-METHYLENE BETA-LACTONE AND ITS STRUCTURE [J].

ADAM, W ;

HASEMANN, L .

CHEMISCHE BERICHTE, 1990, 123 (06) :1449-1451

[2]

AIMAKOV OA, 1998, SERIYA KHIMICHESKAYA, P53

[3]

ALBARBARY AA, 1984, INDIAN J CHEM B, V23, P770

[4] How to freely change the polarity of the stationary phase in a liquid chromatographic column [J].

Andersson, JT ;

Kaiser, G .

ANALYTICAL CHEMISTRY, 1997, 69 (04) :636-642

[5] New [M(R,R′timdt)2] metal-dithiolenes and related compounds (M = Ni, Pd, Pt;: R,R′timdt = monoanion of disubstituted imidazolidine-2,4,5-trithiones):: An experimental and theoretical investigation [J].

Aragoni, MC ;

Arca, M ;

Demartin, F ;

Devillanova, FA ;

Garau, A ;

Isaia, F ;

Lelj, F ;

Lippolis, V ;

Verani, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (30) :7098-7107

[6] New perspectives in phosphonodithioate coordination chemistry. Synthesis and X-ray crystal structure of trans-bis-[O-ethyl(4-methoxyphenyl)phosphonodithioato] nickel(II) [J].

Arca, M ;

Cornia, A ;

Devillanova, FA ;

Fabretti, AC ;

Isaia, F ;

Lippolis, V ;

Verani, G .

INORGANICA CHIMICA ACTA, 1997, 262 (01) :81-84

[7]

Atzrodt J, 2000, EUR J ORG CHEM, V2000, P1661

[8] SOME PROPERTIES OF 4-THIONFLAVONE AND ITS METHIODIDE, AND OF 4-THIONCHROMONES [J].

BAKER, W ;

HARBORNE, JB ;

OLLIS, WD .

JOURNAL OF THE CHEMICAL SOCIETY, 1952, (APR) :1303-1309

[9] REACTIONS OF 4-THIONCHROMONES WITH AMINO-COMPOUNDS, AND WITH METHYL IODIDE [J].

BAKER, W ;

CLARKE, GG ;

HARBORNE, JB .

JOURNAL OF THE CHEMICAL SOCIETY, 1954, (MAR) :998-1002

[10] RAFTing down under: Tales of missing radicals, fancy architectures, and mysterious holes [J].

Barner-Kowollik, C ;

Davis, TP ;

Heuts, JPA ;

Stenzel, MH ;

Vana, P ;

Whittaker, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (03) :365-375

← 1 2 3 4 5 6 7 8 9 10 →