Synthesis and characterization of novel μ-oxamido copper(II) binuclear complexes

被引：0
|
作者：
Zheng, GX [1 ]
Zhang, GY [1 ]
Wang, QF [1 ]
Baomeng [1 ]
Zhang, ZW [1 ]
机构：
[1] Shangdong Bldg Mat Inst, Dept Appl Chem, Shandong 250022, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1998年 / 28卷 / 07期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Six novel mu-oxamido copper(II) binuclear complexes have been prepared and identified as [CuLCu(obze)]ClO4. xH(2)O and [CuLCu(obzp)]ClO4. xH(2)O [obzeH(3) = N-(5-bromobenzoato)-N'-(2-aminoethyl)oxamid, obzpH(3) = N-(5-bromobenzoato)-N'-(2-aminopropyl)oxamid, and L = 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen), or 4,4'-bimethyl-2,2'-bipyridine (Mebipy)]. Based on elemental analyses, IR, UV spectroscopy and.molar conductance analyses, the complexes are proposed to have an oxamido-bridged structure and with Cu(II) in a planar environment.
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页码：1079 / 1089
页数：11
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