Supramolecular structural transformation of N,N′-bis(4-pyridylmethyl)-naphthalene diimide and fluorescence water sensing

被引:12
作者
Li, Guo-Bi [1 ]
Yang, Qing-Yuan [3 ]
Pan, Rong-Kai [1 ]
Liu, Shenggui [1 ]
Xu, Yao-Wei [2 ]
机构
[1] Lingnan Normal Univ, Sch Chem & Chem Engn, Zhanjiang 524048, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
[3] Univ Limerick, Bernal Inst, Dept Chem Sci, Limerick, Ireland
基金
中国国家自然科学基金;
关键词
SINGLE-CRYSTAL TRANSFORMATION; BONDED ORGANIC FRAMEWORK; COORDINATION POLYMERS; LUMINESCENCE; COMPLEXES; ENCAPSULATION; CONSTRUCTION; ADSORPTION; SEPARATION; DIVERSITY;
D O I
10.1039/c6nj04018g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A supramolecular structure based on N,N'-bis(4-pyridylmethyl)-naphthalene diimide exhibits reversible phase transitions in a single-crystal-to-single-crystal process. Such temperature induced SC-SC transformations are driven by intermolecular pi-pi interactions and hydrogen bond interaction. Interestingly, the dynamic supramolecular structure shows selective adsorption and fluorescence water sensing.
引用
收藏
页码:6160 / 6166
页数:7
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