ADSORPTION OF TURQUOISE BLUE QG REACTIVE DYE ON COMMERCIAL ACTIVATED CARBON IN BATCH REACTOR: KINETIC AND EQUILIBRIUM STUDIES

被引:38
作者
Schimmel, D. [1 ]
Fagnani, K. C. [1 ]
Oliveira dos Santos, J. B. [1 ]
Barros, M. A. S. D. [2 ]
da Silva, E. Antonio [1 ]
机构
[1] Western State Univ Parana, BR-85903000 Toledo, PR, Brazil
[2] Univ Estadual Maringa, Dept Chem Engn, BR-87020900 Maringa, Parana, Brazil
关键词
Reactive dye; Activated carbon; Adsorption; Isotherm; Kinetics; Enthalpy of adsorption; AGRICULTURAL WASTE; AQUEOUS-SOLUTION; REMOVAL; ISOTHERM; PHASE; ASH;
D O I
10.1590/S0104-66322010000200007
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The adsorption of reactive turquoise blue QG dye on commercial activated carbon was investigated in a batch reactor to obtain isotherm and kinetic data under different experimental conditions. The adsorbent was characterized by a FTIR method to analyze surface area and pH(PZC) and to identify functional groups. Experiments were conducted to obtain equilibrium data at 30 degrees C, with the pH effect being assayed in the range of 2 to 8. Experiments were then carried out under the optimal pH condition for dye removal to obtain equilibrium data at 30 degrees C, 45 degrees C and 60 degrees C. Adsorption isotherm models were used to correlate the equilibrium data. Maximum dye removal capacity was observed at a pH of 2 and temperature of 30 degrees C. The kinetic experiments were carried out at a pH of 2 and at three different temperatures: 30 degrees C, 45 degrees C and 60 degrees C. Pseudo-second-order models were used to describe the kinetics of dye adsorption.
引用
收藏
页码:289 / 298
页数:10
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