Cyclic Water Clusters in Tape-Like and Cage-Like Structures

被引：6
作者：
Huang, Qin [1 ,2 ]
Diao, Lihong [1 ]
Zhang, Chuang [1 ]
Lei, Fuhou [1 ,2 ]
机构：
[1] Guangxi Univ Nationalities, Coll Chem & Ecol Engn, Nanning 530006, Peoples R China
[2] Key Lab Dev & Applicat Forest Chem Guangxi, Nanning 530006, Peoples R China
来源：
MOLECULES | 2011年 / 16卷 / 04期
基金：
中国博士后科学基金;
关键词：
complexes; water clusters; negatively charge; host-guest; 1,3,5-BENZENETRICARBOXYLIC ACID; SUPRAMOLECULAR COMPLEX; HEXAMER CLUSTERS; SOLID-STATE; AB-INITIO; FRAMEWORK; PENTAMERS; MOLECULES; CHAINS; H2SO4;
D O I：
10.3390/molecules16042871
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Controlling the ratio of 2,2'-bpy to benzene-1,3,5-tricarboxylic acid produces two interesting complexes, namely [Co(2,2'-bpy) 3]center dot(SO4).8.5H(2)O (1) and [Cu-2(BTCA) (2,2'-bpy)(4)] (OH)center dot(2,2'-bpy) (0.5).14H(2)O (2) (H(3)BTCA = benzene-1,3,5-tricarboxylic acid, 2,2'-bpy = 2,2'-bipyridine). We report the structural evidence in the solid state of discrete lamellar water cluster conformations. These units are found to act as supramolecular glue in the aggregation of cobalt (II) or copper (II) complexes to give three dimensional cage-like networks through hydrogen-bonding. It is interesting that the structure of complex 1 contains a 3D negatively charged cage.
引用
收藏
页码：2871 / 2883
页数：13
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