The mechanism of 7,8-diaminopelargonate synthase;: the role of S-adenosylmethionine as the amino donor

被引：15

作者：

Breen, RS ^{[1
]}

Campopiano, DJ ^{[1
]}

Webster, S ^{[1
]}

Brunton, M ^{[1
]}

Watt, R ^{[1
]}

Baxter, RL ^{[1
]}

机构：

[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 20期

关键词：

D O I：

10.1039/b310443p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The product of the first transamination step in the reaction catalysed by diaminopelargonate (DAPA) synthase has been shown to be 4-(S-adenosyl)-2-oxobutanoate, which has been trapped as the corresponding alcohol.

引用

页码：3498 / 3499

页数：2

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