The role of precursor-decomposition kinetics in silicon-nanowire synthesis in organic solvents

被引：68

作者：

Lee, DC ^{[1
]}

Hanrath, T ^{[1
]}

Korgel, BA ^{[1
]}

机构：

[1] Univ Texas, Dept Chem Engn, Texas Mat Inst, Ctr Nano & Mol Sci & Technol, Austin, TX 78712 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 23期

关键词：

nanowires; precursors; silicon; supercritical fluids; synthetic methods;

D O I：

10.1002/anie.200463001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Under pressure! The synthesis of crystalline silicon nanowires can be carried out in organic solvents at reaction temperatures of up to 450-500°C under high-pressure conditions. Gold particles are used as seeds, and organosilanes are employed as the silicon source. The decomposition chemistry of the organosilanes determines the quality of the nanowires formed (see picture of an Si nanowire with an Si/Au tip). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3573 / 3577

页数：5

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