Modular segmented hyperbranched copolymers

被引：25

作者：

Bachler, Patricia R. ^{[1
]}

Forry, Kaitlyn E. ^{[1
]}

Sparks, Chelsea A. ^{[1
]}

Schulz, Michael D. ^{[1
]}

Wagener, Kenneth B. ^{[1
]}

Sumerlin, Brent S. ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Ctr Macromol Sci & Engn, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA

来源：

POLYMER CHEMISTRY | 2016年 / 7卷 / 25期

基金：

美国国家科学基金会;

关键词：

CONDENSING VINYL POLYMERIZATION; TRANSFER RADICAL POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; RAFT POLYMERIZATION; ACTIVATED ESTER; INTRAMOLECULAR CYCLIZATION; BRANCHED COPOLYMERS; BLOCK-COPOLYMERS; CLICK CHEMISTRY; STAR POLYMERS;

D O I：

10.1039/c6py00819d

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Modular segmented hyperbranched polymers, amenable to facile post-polymerization functionalization, were created via two distinct approaches. Self-condensing vinyl polymerization via reversible addition-fragmentation chain transfer (RAFT) polymerization and RAFT polymerization with a divinyl comonomer were employed to create well-defined highly branched materials containing activated esters amenable to highly efficient functionalization in a modular manner.

引用

页码：4155 / 4159

页数：5

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