Polyaniline Multiwalled Carbon Nanotube Magnetic Composite Prepared by Plasma-Induced Graft Technique and Its Application for Removal of Aniline and Phenol

被引:158
作者
Shao, Dadong [1 ]
Hu, Jun [1 ]
Chen, Chang Lun [1 ]
Sheng, Guodong [1 ]
Ren, Xuemei [1 ]
Wang, Xiangke [1 ]
机构
[1] Chinese Acad Sci, Inst Plasma Phys, Key Lab Novel Thin Film Solar Cells, Hefei 230031, Peoples R China
基金
中国国家自然科学基金;
关键词
CONDUCTIVE SURFACE; ADSORPTION; SORPTION; POLYMERIZATION; WATER; EXCHANGE;
D O I
10.1021/jp107492g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Aniline molecules were grafted onto multiwalled carbon nanotubes (MWCNTs) by using a plasma-induced grafting technique. The polyaniline (PANI) grafted MWCNTs (PANI/MWCNTs) were characterized by using ultraviolet visible spectrophotometry, X-ray photoelectron spectroscopy, Raman spectroscopy, thermogravimetric analysis differential thermal analysis, and field-emission scanning electron microscopy. The results indicated that the magnetic composite consisting of PANI/MWCNTs was synthesized. The application of PANI/MWCNTs for the removal of aniline and phenol from aqueous solutions was investigated under ambient conditions. The grafted PANI on MWCNTs contributed to the enhancement of the adsorption capacity because of the strong conjugate effect between PANI and organic pollutants. PANI/MWCNTs can be separated and recovered from aqueous solution by magnetic separation. The results show that PANI/MWCNTs are a promising magnetic material for the preconcentration and separation of organic pollutants from large volumes of aqueous solutions in environmental pollution cleanup.
引用
收藏
页码:21524 / 21530
页数:7
相关论文
共 39 条
  • [1] ALIGNED CARBON NANOTUBE ARRAYS FORMED BY CUTTING A POLYMER RESIN-NANOTUBE COMPOSITE
    AJAYAN, PM
    STEPHAN, O
    COLLIEX, C
    TRAUTH, D
    [J]. SCIENCE, 1994, 265 (5176) : 1212 - 1214
  • [2] Comparative study of first- and second-order Raman spectra of MWCNT at visible and infrared laser excitation
    Antunes, E. F.
    Lobo, A. O.
    Corat, E. J.
    Trava-Airoldi, V. J.
    Martin, A. A.
    Verissimo, C.
    [J]. CARBON, 2006, 44 (11) : 2202 - 2211
  • [3] An assay for ascorbic acid based on polyaniline-coated microplates
    Bossi, A
    Piletsky, SA
    Piletska, EV
    Righetti, PG
    Turner, APF
    [J]. ANALYTICAL CHEMISTRY, 2000, 72 (18) : 4296 - 4300
  • [4] Postpolymerization grafting of aniline tetramer on polythiophene chain: Structural organization of the product and its electrochemical and spectroelectrochemical properties
    Buga, K
    Majkowska, A
    Pokrop, R
    Zagorska, M
    Djurado, D
    Pron, A
    Oddou, JL
    Lefrant, S
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (23) : 5754 - 5762
  • [5] Amino group introduction onto multiwall carbon nanotubes by NH3/Ar plasma treatment
    Chen, Changlun
    Liang, Bo
    Lu, Di
    Ogino, Akihisa
    Wang, Xiangke
    Nagatsu, Masaaki
    [J]. CARBON, 2010, 48 (04) : 939 - 948
  • [6] Synthesis of disulfide-containing aniline and copolymerization with aniline
    Cho, JS
    Sato, S
    Takeoka, S
    Tsuchida, E
    [J]. MACROMOLECULES, 2001, 34 (09) : 2751 - 2756
  • [7] Short-term interactions of aniline and benzidine with three soils in both natural and artificial matrices
    Donaldson, Francis P.
    Nyman, Marianne C.
    [J]. CHEMOSPHERE, 2006, 65 (05) : 854 - 862
  • [8] Induced magnetic ordering by proton irradiation in graphite -: art. no. 227201
    Esquinazi, P
    Spemann, D
    Höhne, R
    Setzer, A
    Han, KH
    Butz, T
    [J]. PHYSICAL REVIEW LETTERS, 2003, 91 (22)
  • [9] Modeling abiotic processes of aniline in water-saturated soils
    Fábrege-Duque, JR
    Jafvert, CT
    Li, H
    Lee, LS
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (09) : 1687 - 1693
  • [10] Removing organic compounds from aqueous medium via wet peroxidation by gold catalysts
    Han, Yi-Fan
    Phonthammachai, Nopphawan
    Ramesh, Kanaparthi
    Zhong, Ziyi
    White, Tim
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (03) : 908 - 912