Mechanism of the Zn(II)/Zn(Hg) reduction inhibited by liquid expanded organic films in aprotic solvents of high dielectric constant

被引：3

作者：

Anastopoulos, AG ^{[1
]}

机构：

[1] Aristotelian Univ Salonika, Dept Chem, Phys Chem Lab, GR-54006 Thessloniki, Greece

来源：

ELECTROCHIMICA ACTA | 1998年 / 43卷 / 16-17期

关键词：

inhibited; reduction; aprotic solvent;

D O I：

10.1016/S0013-4686(97)10163-3

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The mechanism of the electroreduction of Zn(II) at the dropping Hg electrode, inhibited by adsorbed triphenylphosphine oxide, is studied in solutions of pure acetonitrile and propylene carbonate. The aprotic character of the solvents and the expanded liquid nature of the inhibitor film impose a somewhat different approach to the analysis of the kinetic data obtained from de polarographic experiments. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2273 / 2279

页数：7

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