Synthesis of p-conjugated asymmetric aza-BODIPYs via nitrosobicyclopyrroles

被引：4
|
作者：
Mori, Ryota [1 ]
Asakura, Minenari [1 ]
Kobayashi, Yukinori [1 ]
Mashimo, Hiromu [1 ]
Roppongi, Makoto [2 ]
Ito, Satoshi [1 ]
机构：
[1] Utsunomiya Univ, Fac Engn, Dept Appl Chem, 7-1-2 Yoto, Utsunomiya, Tochigi 3218585, Japan
[2] Utsunomiya Univ, Ctr Ind Univ Innovat Support, 7-1-2 Yoto, Utsunomiya, Tochigi 3218585, Japan
来源：
TETRAHEDRON LETTERS | 2022年 / 96卷
关键词：
Nitrosopyrrole; Aza-BODIPY; Near IR dyes; Retro Diels-Alder reaction; DYES; COMPLEXES;
D O I：
10.1016/j.tetlet.2022.153759
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
pi Conjugated aza-BODIPYs with absorption in the near-infrared region have attracted attention, but there are few reports of their synthesis. We report the synthesis and absorption properties of pi-conjugated asymmetric aza-BODIPYs by nitrosation and retro-Diels-Alder reaction of bicyclo[2.2.2]octadiene-fused bicyclopyrroles. We also synthesized aza-BODIPY fused with [2.3]naphtho and [2.3]anthra structures, and pi-conjugated aza-O-chelate BODIPY for the first time by this method. (C) 2022 Elsevier Ltd. All rights reserved.
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页数：6
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