Synthesis, structure, and properties of the thermolysis products of [Os(NH3)5Cl][ReCl6]

被引：5
|
作者：
Yusenko, K. V. [1 ]
Korolkov, I. V. [1 ]
Gromilov, S. A. [1 ]
Korenev, S. V. [1 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 48卷 / 02期
关键词：
X-ray diffraction analysis; X-ray phase analysis; solid substitution solutions; rhenium; osmium;
D O I：
10.1007/s10947-007-0057-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of [Os(NH3)(5)Cl][ReCl6] has been refined by X-ray powder analysis: a = 11.645(3) angstrom, b = 8.3788(2) angstrom, c = 15.277(4) angstrom, beta = 91.029(6)degrees, V = 1490(1) angstrom(3), d(x) = 3.163 g/cm(3), space group P2(1)/m, Z = 4. The thermolysis product of the salt in a hydrogen atmosphere is a solid substitution solution Os0.5Re0.5: a = 2.753(2) angstrom, c = 4.366(3) angstrom, space group P6(3)/mmc; coherent scattering region (CSR) is similar to 230 angstrom.
引用
收藏
页码：379 / 382
页数：4
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