A Saturated and Unsaturated Backbone of the Products from the Reaction of 1,2-Diimine with Aluminum Precursors

被引：6

作者：

Ju, Yingxin ^{[1
]}

Yang, Zhi ^{[1
]}

Ma, Xiaoli ^{[1
]}

Yang, Ying ^{[3
]}

Roesky, Herbert W. ^{[2
]}

机构：

[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

[3] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2015年 / 641卷 / 3-4期

基金：

北京市自然科学基金;

关键词：

1,2-Diimine; Aluminum hydride; Addition; Lithium; Bromide; MAGNESIUM COMPLEXES; POLYMERIZATION; CATALYSTS; HYDROXIDE; ETHYLENE;

D O I：

10.1002/zaac.201400611

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An aluminum(III) monohydride [(2, 6-iPr(2)C(6)H(3))NC(Me)](2)AlH(NMe3) (1) was synthesized by oxidative addition of 1, 2-diimine (L) {L = [(2, 6-iPr(2)C(6)H(3))NC(Me)](2)} with equivalent amounts of H3AlNMe3. A lithium salt (LLi2) was obtained when L was treated with elemental lithium. Under these conditions 1, 2-diimine is reduced to LLi2 with simultaneous formation of a C=C bond. The LLi2 is formed in-situ and treated with AlBr3 to result in the formation of aluminum(III) monobromide [(2, 6-iPr(2)C(6)H(3))NC(Me)](2)AlBr(OEt2) (2). The two products 1 and 2 show a saturated as well as an unsaturated backbone of the ligand.

引用

页码：521 / 524

页数：4

共 28 条

[1] A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer [J].

Clark, Timothy J. ;

Robertson, Nicholas J. ;

Kostalik, Henry A. ;

Lobkovsky, Emil B. ;

Mutolo, Paul F. ;

Abruna, Hector D. ;

Coates, Geoffrey W. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (36) :12888-+

[2] THE POLYMERIZATION OF EPOXIDES BY METAL HALIDE CATALYSTS [J].

COLCLOUGH, RO ;

GEE, G ;

HIGGINSON, WCE ;

JACKSON, JB ;

LITT, M .

JOURNAL OF POLYMER SCIENCE, 1959, 34 (127) :171-179

[3] THE POLYMERIZATION OF PROPYLENE OXIDE BY TRIMETHYL ALUMINUM [J].

COLCLOUGH, RO ;

GEE, G ;

JAGGER, AH .

JOURNAL OF POLYMER SCIENCE, 1960, 48 (150) :273-278

[4] Living alkene polymerization: New methods for the precision synthesis of polyolefins [J].

Domski, Gregory J. ;

Rose, Jeffrey M. ;

Coates, Geoffrey W. ;

Bolig, Andrew D. ;

Brookhart, Maurice .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (01) :30-92

[5] Syntheses and Structures of Magnesium Complexes with Reduced α-Diimine Ligands [J].

Gao, Jing ;

Liu, Yanyan ;

Zhao, Yanxia ;

Yang, Xiao-Juan ;

Sui, Yunxia .

ORGANOMETALLICS, 2011, 30 (22) :6071-6077

[6] Ethylene polymerisation by a copper catalyst bearing α-diimine ligands [J].

Gibson, VC ;

Tomov, A ;

Wass, DF ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (11) :2261-2262

[7] STEREOSPECIFIC POLYMERIZATION OF ACETALDEHYDE .1. [J].

ISHIDA, S .

JOURNAL OF POLYMER SCIENCE, 1962, 62 (173) :1-&

[8] The first structurally characterized aluminum compound with two SH groups:: [LAI(SH)2] (L=N(Ar)C(Me)CHC(Me)N(Ar), Ar=2,6-i-Pr2C6H3) and the catalytic properties of the sulfur P(NMe2)3 system [J].

Jancik, V ;

Peng, Y ;

Roesky, HW ;

Li, JY ;

Neculai, D ;

Neculai, AM ;

Herbst-Irmer, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (06) :1452-1453

[9] NEW PD(II)-BASED AND NI(II)-BASED CATALYSTS FOR POLYMERIZATION OF ETHYLENE AND ALPHA-OLEFINS [J].

JOHNSON, LK ;

KILLIAN, CM ;

BROOKHART, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (23) :6414-6415

[10] Synthesis and Reactions of a Redox-Active α-Diimine Aluminum Complex [J].

Li, Jianfeng ;

Zhang, Kun ;

Huang, Hanmin ;

Yu, Ao ;

Hu, Hongfan ;

Cui, Haiyan ;

Cui, Chunming .

ORGANOMETALLICS, 2013, 32 (06) :1630-1635

← 1 2 3 →