Hydrodehalogenation of aromatic chlorides with NaBH4 in the presence of Ni(0) catalysts

被引：15

作者：

Scrivanti, A ^{[1
]}

Vicentini, B ^{[1
]}

Beghetto, V ^{[1
]}

Chessa, G ^{[1
]}

Matteoli, U ^{[1
]}

机构：

[1] Univ Venice, Dept Chem, I-30123 Venice, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 07期

关键词：

hydrodehalogenation; dechlorination; sodium borohydride; nickel catalyst; aromatic chlorides;

D O I：

10.1016/S1387-7003(98)00065-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrodehalogenation of aryl chlorides is carried out using NaBH4 in the presence of an Ni-phosphine catalytic system. The nature of the solvent plays a very important role in determining the efficiency of the system: very high dechlorination rates are obtained using ethanol/pyridine mixtures. (C) 1998 Elsevier Science S.A. All rights reserved.

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页码：246 / 248

页数：3

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