The photooxidative degradation of poly(vinylchloride) - 2. The stabilising action of dibutyltin maleate and trisnitro (1,3-dihydroxyl-2-hydroxylmethyl-2-nitropropane) on PVC from ultraviolet light radiation

被引：5

作者：

Turoti, M ^{[1
]}

Olayemi, JY ^{[1
]}

Adeniyi, JB ^{[1
]}

Peters, O ^{[1
]}

机构：

[1] Ahmadu Bello Univ, Dept Chem, Zaria, Nigeria

来源：

POLYMER DEGRADATION AND STABILITY | 1998年 / 61卷 / 02期

关键词：

D O I：

10.1016/S0141-3910(97)00212-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The photooxidative degradation and stabilisation of poly(vinylchloride) (PVC) have been studied using dibutyltin maleate (DBTM) alone and mixed with varying amounts of trisnitro (1,3-dihydroxyl-2-hydroxylmethyl-2-nitropropane) compounds as stabilisers. Films of the unstabilised and stabilised PVC were exposed to ultraviolet (UV) light ageing at room temperature. The degradation reactions were monitored by IR, colour formation, tensile strength and elongation at break, as well as determination of time to embrittlement. The stabilising action of 7.2x10(-3) mol% DBTM mixed with 10x10(-4) mol% of the lauryl ester of the trisnitro compounds proved most effective in limiting photooxidative reactions in PVC. (C) 1998 Elsevier Science Limited. All rights reserved.

引用

页码：297 / 302

页数：6

共 15 条

[1] THERMAL AND PHOTO-DEGRADATION OF UNSTABILIZED ABS [J].