SYNTHESIS AND CHARACTERIZATION OF POLYSTYRENE SUPPORTED CATALYTICALLY ACTIVE POLY(AMIDOAMINE) DENDRIMER-PALLADIUM NANOPARTICLE CONJUGATES

被引：15

作者：

Krishnan, G. Rajesh ^{[1
]}

Sreekumar, Krishnapillai ^{[1
]}

机构：

[1] Cochin Univ Sci & Technol, Dept Appl Chem, Cochin 682022, Kerala, India

来源：

SOFT MATERIALS | 2010年 / 8卷 / 02期

关键词：

Dendrimer; Nanoparticles; Palladium; Polymer-supported catalyst; Suzuki coupling reaction; ENCAPSULATED METAL NANOPARTICLES; CROSS-COUPLING REACTION; SUZUKI-MIYAURA REACTION; HIGHLY EFFICIENT; CATALYST; PHOSPHINE; COMPLEXES; CHEMISTRY; DENDRONS; NICKEL;

D O I：

10.1080/15394451003756225

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Poly(amidoamine) dendrimers were synthesized on cross-linked aminomethyl polystyrene. Palladium complexes of supported dendrimers prepared by ligand exchange method were reduced to dendrimer-nanoparticle conjugates supported on polystyrene resin. The supported nanoparticles were used as heterogeneous catalysts for the Suzuki coupling between aryl boronic acids and aryl halides. Various factors affecting the catalysts performance were studied. Higher generation dendrimers gave well-defined nanoparticles without agglomeration and these particles showed good catalytic performance.

引用

页码：114 / 129

页数：16

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