Dioxygen mediated oxo-transfer to an amine and oxidative N-dealkylation chemistry with a dinuclear copper complex

被引：22

作者：

Zhang, CX

Liang, HC

Kim, E

Gan, QF

Tyeklár, Z

Lam, KC

Rheingold, AL

Kaderli, S

Zuberbühler, AD

Karlin, KD

机构：

[1] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA

[2] Univ Delaware, Dept Chem, Newark, DE 19716 USA

[3] Univ Basel, Inst Anorgan Chem, CH-4056 Basel, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 07期

关键词：

D O I：

10.1039/b009053k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of dioxygen with a dinuclear copper(I) complex of a new binucleating ligand is described, wherein a peroxodicopper(II) (Cu-2-O-2) intermediate leads to an ore-transfer reaction to give an N-oxide of an N-benzyl internal ligand substrate; additionally observed regioselective oxidative N-dealkylation chemistry occurs.

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收藏

页码：631 / 632

页数：2

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