Thermal Stability and Electrical Properties of Polyaniline Synthesized by Oxidative Polymerization Method

被引:13
作者
Kumar, Anil [1 ]
Mishra, Amit [1 ]
Awasthi, Kamlendra [2 ]
Kumar, Vinod [1 ]
机构
[1] Malaviya Natl Inst Technol, Dept Met & Mat Engn, Jaipur 302017, Rajasthan, India
[2] Malaviya Natl Inst Technol, Dept Phys, Jaipur 302017, Rajasthan, India
关键词
dodecyl benzene sulfonic acid; polyaniline; sodium dodecyl sulfate;
D O I
10.1002/masy.201400218
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Conducting Polyaniline (PANI) was prepared using oxidative polymerization method by using surfactant sodium dodecyl sulfate (SDS), dodecyl benzene sulfonic acid (DBSA) with dopant hydrochloric acid (HCl). Samples were characterized by X-ray diffraction (XRD), Raman Spectroscopy, thermogravimetric analysis (TGA) and electrical conductivity. XRD confirms the formation of PANI-SDS and PANI-DBSA. It also shows its high degree of crystallinity. Raman spectroscopy results confirm emeraldine form of PANI. Electrical measurements indicate conducting nature of PANI. Thermal degradation of synthesized material starts after 100 degrees C.
引用
收藏
页码:168 / 172
页数:5
相关论文
共 20 条
  • [1] [Anonymous], INT J PLAST TECHNOL
  • [2] Polyaniline by new miniemulsion polymerization and the effect of reducing agent on conductivity
    Bhadra, Sambhu
    Singha, Nikhil K.
    Khastgir, Dipak
    [J]. SYNTHETIC METALS, 2006, 156 (16-17) : 1148 - 1154
  • [3] Dib F. I. E., 2012, J APP POLYM SCI, V124, P3200
  • [4] Synthesis, processing and material properties of conjugated polymers
    Feast, WJ
    Tsibouklis, J
    Pouwer, KL
    Groenendaal, L
    Meijer, EW
    [J]. POLYMER, 1996, 37 (22) : 5017 - 5047
  • [5] Synthesis and characterization of red mud/polyaniline composites:: Electrical properties and thermal stability
    Goek, Ayseguel
    Omastova, Maria
    Prokes, Jan
    [J]. EUROPEAN POLYMER JOURNAL, 2007, 43 (06) : 2471 - 2480
  • [6] Preparation and characterization of polyaniline nanoparticles synthesized from DBSA micellar solution
    Han, MG
    Cho, SK
    Oh, SG
    Im, SS
    [J]. SYNTHETIC METALS, 2002, 126 (01) : 53 - 60
  • [7] Raman study of polyaniline nanofibers prepared by interfacial polymerization
    Jain, Manu
    Annapoorni, S.
    [J]. SYNTHETIC METALS, 2010, 160 (15-16) : 1727 - 1732
  • [8] Preparation and characterization of electromagnetic functionalized polyaniline/BaFe12O19 composites
    Jiang, Jing
    Ai, Lun-Hong
    Qin, Da-Bin
    Liu, Hui
    Li, Liang-Chao
    [J]. SYNTHETIC METALS, 2009, 159 (7-8) : 695 - 699
  • [9] Synthesis and thermoelectric properties of hydrochloric acid-doped polyaniline
    Li, Junjie
    Tang, Xinfeng
    Li, Han
    Yan, Yonggao
    Zhang, Qingjie
    [J]. SYNTHETIC METALS, 2010, 160 (11-12) : 1153 - 1158
  • [10] MacDiarmid AG, 2001, ANGEW CHEM INT EDIT, V40, P2581, DOI 10.1002/1521-3773(20010716)40:14<2581::AID-ANIE2581>3.0.CO