Overcharge protection of lithium-ion batteries above 4 V with a perfluorinated phenothiazine derivative

被引：25

作者：

Kaur, Aman Preet ^{[1
]}

Casselman, Matthew D. ^{[1
]}

Elliott, Corrine F. ^{[1
]}

Parkin, Sean R. ^{[1
]}

Risko, Chad ^{[1
,2
]}

Odom, Susan A. ^{[1
]}

机构：

[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA

[2] Univ Kentucky, Ctr Appl Energy Res, 3572 Iron Works Pike, Lexington, KY 40511 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 15期

基金：

美国国家科学基金会;

关键词：

REDOX SHUTTLE ADDITIVES; OVERDISCHARGE PROTECTION; CHEMICAL OVERCHARGE; PERFORMANCE; MECHANISMS; CATHOLYTE;

D O I：

10.1039/c5ta10375d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron-withdrawing substituents are introduced onto the phenothiazine core to raise its oxidation potential for use as a redox shuttle in high-voltage lithium-ion batteries. A perfluorinated derivative oxidizes at 4.3 V vs. Li+/0, and functions for ca. 500 h of 100% overcharge in LiNi0.8Co0.15Al0.05O2/graphite coin cells at a charging rate of C/10.

引用

页码：5410 / 5414

页数：5

共 35 条

[1] Capacity fade mechanisms and side reactions in lithium-ion batteries
Arora, P
White, RE
Doyle, M
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (10) : 3647 - 3667
[2] Safety mechanisms in lithium-ion batteries
Balakrishnan, PG
Ramesh, R
Kumar, TP
[J]. JOURNAL OF POWER SOURCES, 2006, 155 (02) : 401 - 414
[3] Belf L. J. B., 1966, CHEM IND, V6, P238
[4] An All-Organic Non-aqueous Lithium-Ion Redox Flow Battery
Brushett, Fikile R.
Vaughey, John T.
Jansen, Andrew N.
[J]. ADVANCED ENERGY MATERIALS, 2012, 2 (11) : 1390 - 1396
[5] Possible redox shuttle additives for chemical overcharge and overdischarge protection for lithium-ion batteries
Buhrmester, C
Moshurchak, L
Wang, RCL
Dahn, JR
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (02) : A288 - A294
[6] Studies of aromatic redox shuttle additives for LiFePO4-based Li-ion cells
Buhrmester, C
Chen, J
Moshurchak, L
Jiang, JW
Wang, RL
Dahn, JR
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (12) : A2390 - A2399
[7] The use of 2,2,6,6-tetramethylpiperinyl-oxides and derivatives for redox shuttle additives in Li-ion cells
Buhrmester, Claudia
Moshurchak, L. M.
Wang, R. L.
Dahn, J. R.
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (10) : A1800 - A1804
[8] The fate of phenothiazine-based redox shuttles in lithium-ion batteries
Casselman, Matthew D.
Kaur, Aman Preet
Narayana, Kishore Anand
Elliott, Corrine F.
Risko, Chad
Odom, Susan A.
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (10) : 6905 - 6912
[9] Chemical overcharge and overdischarge protection for lithium-ion batteries
Chen, J
Buhrmester, C
Dahn, JR
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (01) : A59 - A62
[10] Bifunctional electrolyte additive for lithium-ion batteries
Chen, Zonghai
Amine, K.
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (04) : 703 - 707

← 1 2 3 4 →