Fabrication of microtubular reactors coated with thin catalytic layer (M=Pd, Pd-Cu, Pt, Rh, Au)

被引:24
作者
Javaid, Rahat [1 ,2 ]
Kawanami, Hajime [1 ]
Chatterjee, Maya [1 ]
Ishizaka, Takayuki [1 ]
Suzuki, Akira [1 ]
Suzuki, Toshishige M. [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Res Ctr Compact Chem Proc, Miyagino Ku, Sendai, Miyagi 9838551, Japan
[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
关键词
Micro tubular reactor; Thin catalytic metal film; Pd-Cu alloy; Catalytic decomposition of dye; FLOW ORGANIC-SYNTHESIS; COMPOSITE MEMBRANES; MICROSTRUCTURED REACTORS; HYDROGENATION REACTIONS; PERMEATION PROPERTIES; SUPERCRITICAL WATER; COUPLING REACTIONS; SYNTHESIS MACOS; WET OXIDATION; CAPILLARY;
D O I
10.1016/j.catcom.2010.05.018
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Novel micro tubular reactors composed of Inconel 625 support, TiO2/Ti intermediate layer and thin catalytic metal film (Pd, Pd-Cu alloy, Pt. Rh. and Au) were fabricated by continuous electroless plating technique. The reactors withstood high temperature (400 degrees C) and high pressure (30 MPa) water flow without loss of catalytic metals. The high catalytic efficiency of the reactors was demonstrated by the rapid and complete decomposition of organic dye in the flow system. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1160 / 1164
页数:5
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