Binuclear platinum complexes of 4,5-disubstituted xanthenes

被引：10

作者：

Panunzi, A ^{[1
]}

Giordano, F ^{[1
]}

Orabona, I ^{[1
]}

Ruffo, F ^{[1
]}

机构：

[1] Univ Naples Federico II, Dipartimento Chim, I-80126 Naples, Italy

来源：

INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 04期

关键词：

xanthene; dinuclear complexes; platinum; NMR;

D O I：

10.1016/j.ica.2004.11.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New binucleating ligands based on 4,5-disubstituted xanthenes have been prepared. The ligands, which display either mono(acyl, nitrile) or bi-dentate (diimino, dithioamide) functionalities, can be prepared through simple procedures from commercial sources. The molecules have been used to synthesise dinuclear platinum(II) complexes with coordination numbers 4 or 5. Relevant aspects of their spectroscopic characterisation and reactivity are discussed along with the molecular structure of a representative compound. (c) 2004 Elsevier B.V. All rights reserved.

引用

页码：1217 / 1224

页数：8

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