Deep Oxidative Desulfurization of Dibenzothiophene in Simulated Diesel with Tungstate and H2O2 in Ionic Liquids

被引：18

作者：

Chao, Y. ^{[2
]}

Li, H. ^{[1
]}

Zhu, W. ^{[1
]}

Zhu, G. ^{[1
]}

Yan, Y. ^{[1
]}

机构：

[1] Jiangsu Univ, Coll Chem & Chem Engn, Zhenjiang 212013, Peoples R China

[2] Jiangsu Univ, Coll Pharm, Zhenjiang 212013, Peoples R China

来源：

PETROLEUM SCIENCE AND TECHNOLOGY | 2010年 / 28卷 / 12期

关键词：

catalytic oxidation; desulfurization; extraction; hydrogen peroxide; ionic liquids; LIGHT GAS OIL; ROOM-TEMPERATURE; EXTRACTIVE DESULFURIZATION; SOLVENT-EXTRACTION; CHEMICAL OXIDATION; FUELS; ACID; DENITROGENATION; CATALYST; GASOLINE;

D O I：

10.1080/10916460903030441

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A green extraction and catalytic oxidative desulfurization (ECODS) system composed of simple tungsten-containing catalyst, 30 wt% H2O2, and ionic liquids was discovered suitable for the deep removal of dibenzothiophene (DBT) in simulated diesel. In the case of the system comprising Na2WO4 center dot 2H2O, 30 wt% H2O2 and 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4), the removal of DBT could reach 99.7% at 60 degrees C for 3 hr, which was superior to mere solvent extraction with ionic liquid or catalytic oxidation without ionic liquid. This desulfurization system could be recycled five times with a small decrease in activity.

引用

页码：1242 / 1249

页数：8