Gray to Colorless Switching, Crosslinked Electrochromic Polymers with Outstanding Stability and Transmissivity From Naphthalenediimmide-Functionalized EDOT

被引:57
|
作者
Sassi, Mauro [1 ,2 ]
Salamone, Matteo M. [1 ,2 ]
Ruffo, Riccardo [1 ,2 ]
Mari, Claudio M. [1 ,2 ]
Pagani, Giorgio A. [1 ,2 ]
Beverina, Luca [1 ,2 ]
机构
[1] Univ Milano Bicocca, I-20125 Milan, Italy
[2] INSTM, Dept Mat Sci, I-20125 Milan, Italy
关键词
electrochromism; naphthalenediimmide; PEDOT; crosslinked polymers; spectroelectrochemistry; MULTICOLORED ELECTROCHROMISM; GREEN; COMPLETION; EFFICIENCY; BEHAVIOR; DIIMIDE; PAPER;
D O I
10.1002/adma.201200111
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The design, synthesis, polymerization and full electrochemical and spectroelectrochemical characterization of a new naphtalendiimide-functionalized PEDOT cross-linked electrochromic material is reported. The polymer shows exceptionally high redox reversibility, almost complete colorlessness in the bleached state and a gray color in the reduced state Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
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页码:2004 / 2008
页数:5
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