Inverse gas chromatography study of acid-base properties of cation resins used as catalysts of Bisphenol A synthesis

被引:0
|
作者
Bialon, M
Hetper, J
Kiedik, M
Glenc, J
机构
[1] Univ Opole, Inst Chem, PL-45052 Opole, Poland
[2] Inst Heavy Organ Synth, PL-47225 Kedzierzyn Kozle, Poland
来源
CHEMIA ANALITYCZNA | 2001年 / 46卷 / 05期
关键词
inverse gas chromatography; cation resin; ionite; Bisphenol A; acid-base interactions; catalysis;
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The inverse gas chromatography method have been used for estimation of the relative number of acid and base active centres for two types of cation exchangers that are used as catalysts of Bisphenol A industrial synthesis. It was stated that after a few weeks of the continuous work of reactors filled with the catalysts, the acid base properties of the latter have under.-one significant changes. The number or acid centres decreased while the number of base mitres increased. Simultaneously, the decrease of the yield of the synthesis product was observed.
引用
收藏
页码:647 / 652
页数:6
相关论文
共 50 条
  • [21] Investigation of acid-base and surface characteristics of a thermotropic semifluorinated salicylaldimine liquid crystal by inverse gas chromatography
    Yazici, O.
    Ocak, H.
    Yasa-Sahin, O.
    Sakar, D.
    Cankurtaran, O.
    Karaman, F.
    Bilgin-Eran, B.
    LIQUID CRYSTALS, 2012, 39 (12) : 1421 - 1426
  • [22] Study of the second order transitions and acid-base properties of polymers adsorbed on oxides by using inverse gas chromatography at infinite dilution I. Theory and methods
    Hamieh, T
    Rezzaki, M
    Schultz, J
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 233 (02) : 339 - 342
  • [23] Silanization of siliceous materials, part 3: Modification of surface energy and acid-base properties of silica nanoparticles determined by inverse gas chromatography (IGC)
    Bauer, Frank
    Meyer, Ralf
    Bertmer, Marko
    Naumov, Sergej
    Al-Naji, Majd
    Wissel, Julia
    Steinhart, Martin
    Enke, Dirk
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2021, 618
  • [24] Surface acid-base properties of Cu-BTC and Fe-BTC MOFs. An inverse gas chromatography and n-butylamine thermo desorption study
    Autie-Castro, Giselle
    Reguera, Edilso
    Cavalcante, Celio L., Jr.
    Araujo, Antonio S.
    Rodriguez-Castellon, Enrique
    INORGANICA CHIMICA ACTA, 2020, 507
  • [25] Surface Energy and Lewis Acid-base Characteristics of Lignocellulosic Fibers upon Modification by Chemical Vapor Deposition of Trichloromethylsilane: An Inverse Gas Chromatography Study
    Gamelas, J. A. F.
    Azpeitia, M.
    Ferreira, P. J.
    Tejado, A.
    JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 2018, 38 (03) : 264 - 275
  • [26] In situ spectroscopic insights into the redox and acid-base properties of ceria catalysts
    Wang, Xiang
    Li, Meijun
    Wu, Zili
    CHINESE JOURNAL OF CATALYSIS, 2021, 42 (12) : 2122 - 2140
  • [27] Inverse gas chromatography as a tool for screening materials: The relation between Lewis acid-base constants and triboelectric charge density of polymers
    Shi, Baoli
    JOURNAL OF CHROMATOGRAPHY A, 2022, 1675
  • [28] Inverse Gas Chromatography for Determining the Surface Free Energy and Acid-Base Chemical Characteristics of a Water Extracted Hardwood (Acer rubrum)
    Mills, Ryan H.
    Jara, Rory
    Gardner, Douglas J.
    van Heiningen, Adriaan
    JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 2009, 29 (01) : 11 - 23
  • [29] Determination of the acid/base properties of MgY and NH4Y molecular sieves by inverse gas chromatography
    Bilgic, Ceyda
    Tumsek, Fatma
    JOURNAL OF CHROMATOGRAPHY A, 2007, 1162 (01) : 83 - 89
  • [30] The use of inverse gas chromatography to assess the acid-base contributions to surface energies of cefditoren pivoxil and methacrylate copolymers and possible links to instability
    Ohta, M
    Buckton, G
    INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2004, 272 (1-2) : 121 - 128