Inverse gas chromatography study of acid-base properties of cation resins used as catalysts of Bisphenol A synthesis

被引:0
|
作者
Bialon, M
Hetper, J
Kiedik, M
Glenc, J
机构
[1] Univ Opole, Inst Chem, PL-45052 Opole, Poland
[2] Inst Heavy Organ Synth, PL-47225 Kedzierzyn Kozle, Poland
来源
CHEMIA ANALITYCZNA | 2001年 / 46卷 / 05期
关键词
inverse gas chromatography; cation resin; ionite; Bisphenol A; acid-base interactions; catalysis;
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The inverse gas chromatography method have been used for estimation of the relative number of acid and base active centres for two types of cation exchangers that are used as catalysts of Bisphenol A industrial synthesis. It was stated that after a few weeks of the continuous work of reactors filled with the catalysts, the acid base properties of the latter have under.-one significant changes. The number or acid centres decreased while the number of base mitres increased. Simultaneously, the decrease of the yield of the synthesis product was observed.
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页码:647 / 652
页数:6
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