Unlocking the in situ Li plating dynamics and evolution mediated by diverse metallic substrates in all-solid-state batteries

被引:32
作者
Cui, Can [1 ]
Yang, Hui [2 ]
Zeng, Cheng [1 ]
Gui, Siwei [2 ]
Liang, Jianing [1 ]
Xiao, Ping [1 ]
Wang, Shuhao [1 ]
Huang, Guxin [1 ]
Hu, Mingtao [1 ]
Zhai, Tianyou [1 ]
Li, Huiqiao [1 ]
机构
[1] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Hubei, Peoples R China
[2] Huazhong Univ Sci & Technol, Sch Aerosp Engn, Dept Mech, Wuhan 430074, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
LITHIUM; ANODE; STRATEGY;
D O I
10.1126/sciadv.add2000
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The mechanisms of Li deposition behaviors, which overwhelmingly affect battery performances and safety, are far to be understood in solid-state batteries. Here, using in situ micro-nano electrochemical scanning electron microscopy (SEM) manipulation platform, dynamic Li plating behaviors on 10 metallic substrates have been tracked, and the underlying mechanisms for dendrite-free Li plating are elucidated. Distinct Li deposition behaviors on Cu, Ti, Ni, Bi, Cr, In, Ag, Au, Pd, and Al are revealed quantitatively in nucleation densities, growth rates, and anisotropic ratios. For Li alloyable metals, the dynamic Li alloying process before Li growth is visually captured. It is concluded that a good affinity for Li and appropriate lattice compatibility between the substrate and Li are needed to facilitate homogeneous Li plating. Our work not only uncovers the Li plating dynamics, shedding light on the design of solid-state batteries, but also provides a powerful integrated SEM platform for future in-depth investigation of solid-state batteries.
引用
收藏
页数:10
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