Living polymerization of 1,3-butadiene with the catalyst system composed of cyclopentadienyltitanium trichloride and methylaluminoxane

被引：0
|
作者：
Miyazawa, A
Kase, T
Soga, K
机构：
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Tatsunokuchi, Ishikawa 92312, Japan
[2] Japan Chem Innovat Inst, Joint Res Ctr Precis Polymerizat, Tsukuba, Ibaraki 305, Japan
[3] Natl Inst Mat & Chem Res, Dept Polymer Chem, Tsukuba, Ibaraki 305, Japan
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1999年 / 37卷 / 06期
关键词：
1,3-butadiene; cyclopentadienyltitanium trichloride; methylaluminoxane;
D O I：
10.1002/(SICI)1099-0518(19990315)37:6<695::AID-POLA3>3.3.CO;2-U
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A catalyst system composed of CpTiCl3 with MAO proceeded the living polymerization of 1,3-butadiene at -25 degrees C to yield cis-polybutadiene (85% cis-content) with extremely narrow MMD (M-w/M-n = 1.04). The reaction temperature affected the cis-selectivity and living nature of the polymerization of 1,3-butadiene.
引用
收藏
页码：695 / +
页数：4
相关论文
共 21 条
  • [1] cis-specific living polymerization of 1,3-butadiene with CoCl2 and methylaluminoxane
    Nath, DCD
    Shiono, T
    Ikeda, T
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2002, 203 (04) : 756 - 760
  • [2] Kinetic features of the cobalt dihalide/methylaluminoxane catalytic system in 1,3-butadiene polymerization
    Nath, Dilip Chandra Deb
    Fellows, Christopher M.
    Shiono, Takeshi
    MACROMOLECULAR RESEARCH, 2006, 14 (03) : 338 - 342
  • [3] Kinetic features of the cobalt dihalide/methylaluminoxane catalytic system in 1,3-butadiene polymerization
    Dilip Chandra Deb Nath
    Christopher M. Fellows
    Takeshi Shiono
    Macromolecular Research, 2006, 14 : 338 - 342
  • [4] Polymerization of 1,3-butadiene with VO(P204)2 activated by methylaluminoxane, purified methylaluminoxane, and trimethylaluminum
    Wang, Haiying
    Cao, Lihui
    Zhang, Xuequan
    JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 127 (06) : 4594 - 4600
  • [5] Investigation of methylaluminoxane as a cocatalyst for the polymerization of 1,3-butadiene to high cis-1,4-polybutadiene
    Cass, P
    Pratt, K
    Mann, T
    Laslett, B
    Rizzardo, E
    Burford, R
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999, 37 (16) : 3277 - 3284
  • [6] Copolymerization of 1,3-butadiene and isoprene with cobalt dichloride/methylaluminoxane in the presence of triphenylphosphine
    Nath, DCD
    Shiono, T
    Ikeda, T
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (17) : 3086 - 3092
  • [7] Polymerization of 1,3-butadiene by cobalt dichloride activated with various methylaluminoxanes
    Nath, DCD
    Shiono, T
    Ikeda, T
    APPLIED CATALYSIS A-GENERAL, 2003, 238 (02) : 193 - 199
  • [8] Stereospecific Polymerization of 1,3-Butadiene Catalyzed by [NNO] Cobalt Complexes
    Lv, Shuai
    Jie, Su-yun
    ACTA POLYMERICA SINICA, 2015, (12) : 1486 - 1492
  • [9] Stereospecific and molecular weight-controlled polymerization of 1,3-butadiene with Co(acac)3-MAO catalyst
    Endo, K
    Hatakeyama, N
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (16) : 2793 - 2798
  • [10] Synthesis of cationic cobalt( II) complexes and their efficiency as catalysts for the polymerization of 1,3-butadiene
    Liu, Li
    Zhang, Xu
    Liu, Heng
    Zhang, Xuequan
    Sun, Guangping
    Zhang, Hexin
    INORGANICA CHIMICA ACTA, 2014, 414 : 8 - 14
123