Identification of green pigments from fragments of Roman mural paintings of three Roman sites from north of Germania Superior

被引：8

作者：

Debastiani, Rafaela ^{[1
,2
]}

Simon, Rolf ^{[1
]}

Goettlicher, Joerg ^{[1
]}

Heissler, Stefan ^{[4
]}

Steininger, Ralph ^{[1
]}

Batchelor, David ^{[1
]}

Fiederle, Michael ^{[1
,3
]}

Baumbach, Tilo ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, IPS, IBPT, ANKA, Eggenstein Leopoldshafen, Germany

[2] Univ Freiburg, Fac Environm & Nat Resources, Freiburg, Germany

[3] Univ Freiburg, Freiburg Mat Res Ctr FMF, Freiburg, Germany

[4] Karlsruhe Inst Technol, Inst Funct Interfaces IFG, Eggenstein Leopoldshafen, Germany

来源：

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2016年 / 122卷 / 10期

关键词：

RAMAN-SPECTROSCOPIC ANALYSIS; WALL-PAINTINGS; SYNCHROTRON;

D O I：

10.1007/s00339-016-0400-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Roman mural green pigment painting fragments from three Roman sites in the north of the Roman province Germania Superior: Koblenz Stadtwald Remstecken (KOSR), Weissenthurm "Am guten Mann" (WEIS) and Mendig Lungenkarchen (MELU), dating from second and third centuries AD were analyzed. The experiments were performed nondestructively using synchrotron-based scanning macro-X-ray fluorescence (SR-MA-XRF), synchrotron-based scanning micro-X-ray fluorescence (SR-mu-XRF), synchrotron-based X-ray diffraction (SR-XRD) and Raman spectroscopy. Correlation between SR-MA-XRF, SR-mu-XRF elemental map distributions and optical images of scanned areas was mainly found for the elements Ca, Fe and K. With XRF, Fe and K were identified correlated with green pigment, but in samples from two sites, Mendig Lungenkarchen and Weissenthurm "Am guten Mann", also Cu was detected in minor concentration. The results of SR-XRD and Raman spectroscopy were limited to one sample from Weissenthurm "Am guten Mann". In this sample, green earth and calcium carbonate were identified by SR-XRD and, additionally, malachite by Raman spectroscopy.

引用

页数：12

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