Mechanochemically synthesised dicyanamide hybrid organic-inorganic perovskites, and their melt-quenched glasses

被引：7

作者：

McHugh, Lauren N. ^{[1
]}

Thorne, Michael F. ^{[1
]}

Chester, Ashleigh M. ^{[1
]}

Etter, Martin ^{[2
]}

Uzarevic, Krunoslav ^{[3
]}

Bennett, Thomas D. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Mat Sci & Met, 27 Charles Babbage Rd, Cambridge CB3 0FS, Cambs, England

[2] DESY, FS PETRA D, P02-1,Notkestr 85, D-22607 Hamburg, Germany

[3] Rudjer Boskovic Inst, Zagreb, Croatia

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 24期

关键词：

METAL; FRAMEWORK; EFFICIENT;

D O I：

10.1039/d2cc00278g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we present efficient and scalable mechanochemical formation of hybrid organic-inorganic perovskites of the form [TPrA][M(dca)(3)] (M = Mn2+, Co2+) and the subsequent formation of their bulk melt-quenched glasses. In situ X-ray diffraction reveals direct, facile, and almost instantaneouos formation of both crystalline materials, while slow cooling limits recrystallisation in glasses. The glasses show good stability to acidic and basic aqueous solutions and display higher carbon dioxide uptakes than their crystalline precursors.

引用

页码：3949 / 3952

页数：4

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