Polymer Brush Modified Electrode with Switchable Selectivity Triggered by pH Changes Enhanced by Gold Nanoparticles

被引:0
|
作者
Sempionatto, Juliane R. [1 ]
Pedrosa, Valber A. [1 ]
机构
[1] UNESP, Dept Chem & Biochem, Inst Biosci, Botucatu, SP, Brazil
来源
INTERNATIONAL CONFERENCE ON MATERIAL SCIENCE AND MATERIAL ENGINEERING (MSME 2014) | 2014年
关键词
Polyacrylic Acid (PAA); LSPR; polymer brush; pH sensor; BIOELECTROCATALYSIS;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work a pH sensor was build up with smart material based on polymer brush and gold nanoparticles. The modified electrode functionalized with a polymer brush Polyacrylic Acid (PAA) tethered to the surface and covered with gold nanoparticle (ITO/PAA/Au) demonstrated switchable interfacial properties discriminating different pHs. The switchable electrochemical and plasmonic process was characterized by differential pulse voltammetry (DPV), Faradaic impedance spectroscopy (EIS), cyclic voltammetry (CV) and Localized Surface Plasmon Resonance (LSPR).
引用
收藏
页码:271 / 277
页数:7
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