Electron paramagnetic resonance and optical studies Of CU2+ doped bis(thiourea)cadmium chloride single crystal

被引：5

作者：

Ravi, S. ^{[1
]}

Subramanian, P. ^{[1
]}

机构：

[1] Gandhigram Rural Univ, Dept Phys, Dindigul 624302, Tamil Nadu, India

来源：

SOLID STATE SCIENCES | 2007年 / 9卷 / 10期

关键词：

epr; cu(2+); nlo;

D O I：

10.1016/j.solidstatesciences.2007.07.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electron paramagnetic resonance (EPR) and optical studies have been carried out on Cu2+ doped bis(thiourea)cadmium chloride single crystal, which belongs to a potential semi-organic non-linear material, at room temperature. The spin Hamiltonian parameters were determined as g(xx) = 2.04331, g(yy) = 2.04373, g(zz) = 2.05750 and A(xx) = 91G, A(yy) = 115G, A(zz) = 136G. These parameters suggest that the spectroscopic splitting parameter g and hyperfine splitting parameter A exhibit rhombic symmetry. The optical study reveals that the non-linear optical property of the host lattice has been enhanced due to Cu2+ doping. (c) 2007 Elsevier Masson SAS. All rights reserved.

引用

页码：961 / 963

页数：3

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