Axially chiral C2-symmetric N-heterocyclic carbene (NHC) palladium complex-catalyzed asymmetric α-hydroxylation of β-keto esters

被引：28

作者：

Cao, Shu-Hua ^{[1
,2
]}

Shi, Min ^{[1
,2
,3
]}

机构：

[1] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China

[2] E China Univ Sci & Technol, Inst Fine Chem, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 2010年 / 21卷 / 21-22期

基金：

中国国家自然科学基金;

关键词：

ATOM-TRANSFER; ADDITIONS; ENOLATE; OXYGEN;

D O I：

10.1016/j.tetasy.2010.10.031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Axially chiral C-2-symmetric N-heterocyclic carbene (NHC) palladium diaquo complexes 1a and 1b derived from (R)-BINAM are effective catalysts for the enantioselective alpha-hydroxylation of beta-keto esters using oxaziridine 2a as the oxidant to give the corresponding products in high yields along with moderate enantioselectivities (C) 2010 Elsevier Ltd All rights reserved

引用

页码：2675 / 2680

页数：6

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