Prospect of Sulfurized Pyrolyzed Poly(acrylonitrile) (S@pPAN) Cathode Materials for Rechargeable Lithium Batteries

被引:152
作者
Yang, Huijun [1 ]
Chen, Jiahang [1 ]
Yang, Jun [1 ]
Wang, Jiulin [1 ,2 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai Electrochem Energy Devices Res Ctr, Shanghai 200240, Peoples R China
[2] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
battery safety; interfacial regulation; lithium-sulfur batteries; S@pPAN cathode; solid-solid conversion; LONG CYCLE LIFE; COMPOSITE CATHODE; ELECTROCHEMICAL PERFORMANCE; POLYACRYLONITRILE CATHODE; CARBON; ELECTROLYTE; STORAGE; ION; POLYSULFIDE; BINDER;
D O I
10.1002/anie.201913540
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lithium-sulfur (Li-S) batteries are one of the most promising next-generation batteries owing to their ultra-high theoretical energy density and that sulfur is an abundant resource. During the past 20 years, various sulfur materials have been reported. As a molecular-scale sulfur-composite cathode, sulfurized pyrolyzed poly(acrylonitrile) (S@pPAN) exhibits several competitive advantages in terms of its electrochemical behavior. Although it was first reported in 2002 S@pPAN is currently attracting increasing attention. In this Minireview, we summarize its molecular model and explore the correlation between its structure and its exceptional electrochemical performance. We classify the modification strategies into three types, including material improvement, binder, and electrolyte screening. Several research and development directions are also suggested.
引用
收藏
页码:7306 / 7318
页数:13
相关论文
共 109 条
[61]   Preparation, characterization and swelling behaviors of polyurethane-grafted calcium alginate hydrogels [J].
Wang, Jichao ;
Ying, Xiaoguang ;
Li, Xiao ;
Zhang, Weiying .
MATERIALS LETTERS, 2014, 126 :263-266
[62]   Room temperature Na/S batteries with sulfur composite cathode materials [J].
Wang, Jiulin ;
Yang, Jun ;
Nuli, Yanna ;
Holze, Rudolf .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (01) :31-34
[63]   Sulfur-Based Composite Cathode Materials for High-Energy Rechargeable Lithium Batteries [J].
Wang, Jiulin ;
He, Yu-Shi ;
Yang, Jun .
ADVANCED MATERIALS, 2015, 27 (03) :569-575
[64]   Towards a Safe Lithium-Sulfur Battery with a Flame-Inhibiting Electrolyte and a Sulfur-Based Composite Cathode [J].
Wang, Jiulin ;
Lin, Fengjiao ;
Jia, Hao ;
Yang, Jun ;
Monroe, Charles W. ;
NuLi, Yanna .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (38) :10099-10104
[65]   Hierarchical Sulfur-Based Cathode Materials with Long Cycle Life for Rechargeable Lithium Batteries [J].
Wang, Jiulin ;
Yin, Lichao ;
Jia, Hao ;
Yu, Haitao ;
He, Yushi ;
Yang, Jun ;
Monroe, Charles W. .
CHEMSUSCHEM, 2014, 7 (02) :563-569
[66]   Carbonyl-β-Cyclodextrin as a Novel Binder for Sulfur Composite Cathodes in Rechargeable Lithium Batteries [J].
Wang, Jiulin ;
Yao, Zhendong ;
Monroe, Charles W. ;
Yang, Jun ;
Nuli, Yanna .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (09) :1194-1201
[67]   Sulfur composite cathode materials for rechargeable lithium batteries [J].
Wang, JL ;
Yang, J ;
Wan, CR ;
Du, K ;
Xie, JY ;
Xu, NX .
ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (06) :487-492
[68]  
Wang JL, 2002, ADV MATER, V14, P963, DOI 10.1002/1521-4095(20020705)14:13/14<963::AID-ADMA963>3.0.CO
[69]  
2-P
[70]   Sulfur-carbon nano-composite as cathode for rechargeable lithium battery based on gel electrolyte [J].
Wang, JL ;
Yang, J ;
Xie, JY ;
Xu, NX ;
Li, Y .
ELECTROCHEMISTRY COMMUNICATIONS, 2002, 4 (06) :499-502