Prospect of Sulfurized Pyrolyzed Poly(acrylonitrile) (S@pPAN) Cathode Materials for Rechargeable Lithium Batteries

被引：152

作者：

Yang, Huijun ^{[1
]}

Chen, Jiahang ^{[1
]}

Yang, Jun ^{[1
]}

Wang, Jiulin ^{[1
,2
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai Electrochem Energy Devices Res Ctr, Shanghai 200240, Peoples R China

[2] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 19期

基金：

中国国家自然科学基金;

关键词：

battery safety; interfacial regulation; lithium-sulfur batteries; S@pPAN cathode; solid-solid conversion; LONG CYCLE LIFE; COMPOSITE CATHODE; ELECTROCHEMICAL PERFORMANCE; POLYACRYLONITRILE CATHODE; CARBON; ELECTROLYTE; STORAGE; ION; POLYSULFIDE; BINDER;

D O I：

10.1002/anie.201913540

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium-sulfur (Li-S) batteries are one of the most promising next-generation batteries owing to their ultra-high theoretical energy density and that sulfur is an abundant resource. During the past 20 years, various sulfur materials have been reported. As a molecular-scale sulfur-composite cathode, sulfurized pyrolyzed poly(acrylonitrile) (S@pPAN) exhibits several competitive advantages in terms of its electrochemical behavior. Although it was first reported in 2002 S@pPAN is currently attracting increasing attention. In this Minireview, we summarize its molecular model and explore the correlation between its structure and its exceptional electrochemical performance. We classify the modification strategies into three types, including material improvement, binder, and electrolyte screening. Several research and development directions are also suggested.

引用

页码：7306 / 7318

页数：13

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