A General Palladium Catalyst System for Suzuki-Miyaura Coupling of Potassium Aryltrifluoroborates and Aryl Mesylates

被引:64
作者
Chow, Wing Kin
So, Chau Ming
Lau, Chak Po
Kwong, Fuk Yee [1 ]
机构
[1] Hong Kong Polytech Univ, State Key Lab Chirosci, Kowloon, Hong Kong, Peoples R China
关键词
EFFICIENT CATALYST; TOSYLATES; ARENESULFONATES; SCOPE; AMINOMETHYLATIONS; AMINATION; ALKENYL; LIGANDS; HALIDES; SALTS;
D O I
10.1021/jo100846t
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first general examples of palladium-catalyzed Suzuki-type cross-coupling of aryl and heteroaryl mesylates with potassium aryl and heteroaryltrifluoroborates are presented. In addition to biaryl couplings, the cross-coupling reactions of aryl mesylates with alkyl and vinyltrifluoroborate salts have also been successfully accomplished.
引用
收藏
页码:5109 / 5112
页数:4
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