Homoleptic iron(II) and cobalt(II) bis(phosphoranimide) complexes for the selective hydrofunctionalization of unsaturated molecules

被引：34

作者：

Bai, Tao ^{[1
]}

Janes, Trevor ^{[2
]}

Song, Datong ^{[2
]}

机构：

[1] Shanxi Univ, Coll Chem & Chem Engn, 92 Wucheng Rd, Taiyuan 030006, Shanxi, Peoples R China

[2] Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 37期

关键词：

CATALYZED ASYMMETRIC HYDROGENATION; CARBONYL-COMPOUNDS; ENANTIOSELECTIVE REDUCTION; ALKENE HYDROGENATION; METAL CATALYSTS; NOBEL LECTURE; HYDROBORATION; KETONES; LIGANDS; CATECHOLBORANE;

D O I：

10.1039/c7dt02427d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Low-coordinate homoleptic bulky M-2((NPBu3)-Bu-t)(4) (M = Fe (A), Co (B)) complexes were synthesized and characterized as dimeric structures by crystallographic studies. The iron complex A can catalyze the hydroboration reaction of aldehydes and ketones. The cobalt complex B outperformed its iron counterpart in hydrogenations of several typical alkenes and alkynes under mild conditions. Poisoning experiments indicate that the Co(II)/HBpin catalytic system could be homogeneous.

引用

页码：12408 / 12412

页数：5

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