Corrosion of Ti3SiC2 ceramics in a high-temperature CO environment

被引:5
作者
Istomin, Pavel [1 ]
Istomina, Elena [1 ]
Nadutkin, Aleksandr [1 ]
Grass, Vladislav [1 ]
机构
[1] Russian Acad Sci, Ural Branch, Komi Sci Ctr, Inst Chem, Pervomaiskaya 48, Syktyvkar 167982, Russia
基金
俄罗斯基础研究基金会;
关键词
Ti3SiC2; Ceramics; Corrosion; Microstructure;
D O I
10.1016/j.matlet.2019.126763
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report the results of our experiments on cyclic exposure of Ti3SiC2 ceramics to CO environment at high temperature. The growth of a two-layer scale composed of a dense outer layer containing beta-SiC and TiC microcrystals, and a porous inner layer of TiC microcrystals was observed. The corrosion was accompanied by the release of SiO gas, which then took part in the growth of beta-SiC microcrystals in the upper part of the outer layer by the reaction with CO gas. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页数:5
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