Ferrite thin films: Synthesis, characterization and gas sensing properties towards LPG

Nanocrystalline (Co, Cu, Ni, Zn) ferrite thin films have been deposited onto the Si (100) and alumina substrates by spray pyrolysis deposition technique. Respective metal chlorides and iron chloride were used as precursors. The structural properties of (Co, Cu, Ni, Zn) ferrite thin films were investigated by Xray diffraction (XRD) technique which confirms polycrystalline nature and single phase spinel structure. The surface morphology was studied using scanning electron microscopy (SEM) which reveals spherical morphology for these films except NiFe2O4 films that exhibit petal like structure. The optical transmittance and reflectance measurements were recorded using a double beam spectrophotometer. The optical studies reveal that the transition is direct band gap energy. The VSM analyzes reveal the predominant ferrimagnetic nature for CuFe2O4 films. The gas sensing properties towards Liquid Petroleum Gas (LPG) revealed that ZnFe2O4 films are sensitive at lower temperature while NiFe2O4 films show steep rise at higher temperature. (C) 2014 Elsevier B.V. All rights reserved.