Selective two-phase-hydrogenation of sorbic acid with novel water soluble ruthenium complexes

被引：51
|
作者：
Driessen-Holscher, B [1 ]
Heinen, J [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Tech Chem & Petrolchem, D-52056 Aachen, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 570卷 / 01期
关键词：
ruthenium; water soluble complexes; biphasic hydrogenation; sorbic acid;
D O I：
10.1016/S0022-328X(98)00874-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Neutral and cationic water soluble Cp*-ruthenium-complexes of the type [Cp*Ru(CO)Cl(PR3)] and [Cp*Ru(CO)(PR3)]CF3SO3 (R = CH2OH, (CH2)(3)OH, Ph-m-SO3Na) have been synthesized for the first time and have been used as catalysts in two-phase-hydrogenations. The neutral complexes have been fully characterized. But the cationic complexes which have not been isolated are effective catalysts for the selective hydrogenation of sorbic acid in water/n-heptane leading to the formation of cis-3-hexenoic acid and trans-3-hexenoic acid. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：141 / 146
页数：6
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